4.7 Article

Zinc aluminum-layered double hydroxide(LDH)-graphene oxide(GO) lubricating and corrosion-resistant composite coating on the surface of magnesium alloy

Journal

SURFACE & COATINGS TECHNOLOGY
Volume 437, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2022.128354

Keywords

Magnesium alloys; Graphene oxide; Layered double hydroxides; Corrosion resistance; Wear reduction

Funding

  1. National Natural Science Foundation of China [52105176, 51709049]
  2. National Key Research and Development Program of China [2021YFB3400601]
  3. Program for Guangdong Introducing Innovative and Entrepreneurial Teams [2019TO2Z393]

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Zinc aluminum-layered double hydroxide (ZnAl-LDH) was grown in-situ on the low-pressure cold gas spraying (LPCGS) Al coating by hydrothermal method. The composite coating zinc aluminum-layered double hydroxide-Graphene oxide (LDH-G) was formed by electrostatic adsorption of graphene oxide (GO) and ZnAlLDH. LDH-G coating showed excellent reduction in wear and corrosion resistance, attributed to the good mechanical properties of graphene and the corrosion inhibition effect of ZnAl-LDH.
Zinc aluminum-layered double hydroxide (ZnAl-LDH) was grown in-situ on the low-pressure cold gas spraying (LPCGS) Al coating by hydrothermal method. Then the composite coating zinc aluminum-layered double hydroxide-Graphene oxide (LDH-G) was formed by electrostatic adsorption of graphene oxide (GO) and ZnAlLDH. The structure, morphology, and composition of the coating were studied. A rotational ball-on-disk tribometer (WTM-2E, China) was used to test the tribological properties of the LDH-G coating. The polarization curve and EIS measured the electrochemical properties of the LDH-G coating in 3.5 wt% NaCl solution. Due to the good mechanical properties of graphene and the corrosion inhibition effect of ZnAl-LDH, LDH-G showed an excellent reduction in wear and corrosion resistance.

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