Anode supported planar 5 x 5 cm2 SrZr0.5Ce0.4Y0.1O2.95 based solid oxide protonic fuel cells via sequential tape-casting

Solid oxide protonic fuel cells are one of the most efficient means of directly converting stored chemical energy to usable electrical energy. Acceptor-doped Ba(Zr, Ce)O-3 perovskite-type oxides are the preferred electrolyte choice as they provide higher conductivity due to lower activation energy. While substantial progress has been made on small-sized protonic laboratory-scale cells, a considerable challenge has been upscaling robust planar-type devices. This paper employs a cost-effective inverse tape casting route and screen printing to fabricate flat planar anode-supported protonic fuel cells consisting of NiO-SrZr0.5Ce0.4Y0.1O3-delta substrate, SrZr0.5Ce0.4Y0.1O3-delta electrolyte, and BaCo0.4Fe0.4Zr0.1Y O-0.1(3-delta) as the cathode. The processing parameters were analyzed and adjusted to obtain defect-free single cells of dimension up to 100 mm x 100 mm x 0.5 mm with diminished warping. In addition, the smooth tri-layered green tapes yielded suitably dense and gas-tight electrolyte layers after co sintering at 1300 degrees C/5 h. Finally, the electrochemical performance of the 50 x 50 mm(2) SrZr0.5Ce0.4Y0.1O2.95 based cells was evaluated, and their impedance spectra were deconvoluted to identify all performance-related polarization processes via the distribution of relaxation time.

Automated summary

Solid oxide protonic fuel cells are efficiently converted stored chemical energy to usable electrical energy. This paper presents a cost-effective method for fabricating large-sized planar protonic fuel cells using inverse tape casting and screen printing. The cells exhibited defect-free single cells with suitable density and gas-tight electrolyte layers. The electrochemical performance of the cells based on SrZr0.5Ce0.4Y0.1O2.95 was evaluated and showed promising results.