4.7 Article

Improve solar cell performance of high-performance multicrystalline silicon seeded with low-cost compact nucleation layer

Journal

SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 236, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.solmat.2021.111509

Keywords

High performance multicrystalline silicon; Compact nucleation layer; Nucleation; Dislocation; Conversion efficiency; Shunting

Funding

  1. Natural Science Foundation of China [21971172]
  2. Department of science and technology of Jiangxi Province Key R&D projects,China

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To improve the quality of multicrystalline silicon ingots and solar cells, a compact nucleation layer was designed. The results showed that the compact nucleation layer led to finer and more uniform nucleation grains, and reduced the number of grains with high defect density at the bottom of the ingot. Furthermore, the solar cell efficiency and electrical performance parameters were improved with the use of the compact nucleation layer.
In order to further improve the quality of high efficiency multicrystalline silicon and the performance of multicrystalline silicon solar cells, we designed a compact nucleation layer on the crucible bottom for casting high performance multicrystalline silicon ingots. The morphology of nucleation grains, the minority carrier lifetime mappings and the defects were analyzed and compared with that of the conventional nucleation layer. The results show that the initial nucleation grains of the compact nucleation layer were finer and more uniform, and there are fewer grains with high defect density at the ingot bottom,which is beneficial to reduce the defect ratio of the whole ingot. Moreover, the solar cell efficiency and electrical performance parameters, such as Rsh was also discussed. It was found that the Rsh has a great impact on the efficiency of multi-busbars solar cells, and the average solar cell conversion efficiency of the wafers grown with the compact nucleation layer is 0.11% higher than that of the wafers grown with the conventional nucleation layer.

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