Multi-Decker Emissive Supramolecular Architectures Based on Shape-Complementary Ligands Pair

Dye aggregates have attracted a great deal of attention due to their widespread applications in organic light-emitting devices, light-harvesting systems, etc. However, the strategies to precisely control chromophores with specific spatial arrangements still remain a great challenge. In this work, a series of double- and triple-decker supramolecular complexes are successfully constructed by coordination-driven self-assembly of carefully designed shape-complementary ligands, one claw-like tetraphenylethylene (TPE)-based host ligand and three tetratopic or ditopic guest ligands. The spatial configurations of these assemblies (one double-decker and three S-shaped or X-shaped triple-decker structures) depend on the angles of these TPE-derived ligands. Notably, the three triple-decker structures are geometric isomers. Furthermore, photophysical studies show that these complexes exhibit different ratios of radiative (k(r)) and non-radiative (k(nr)) rate constant due to the different spatial arrangements of TPE moieties. This study provides not only a unique strategy for the construction of multi-stacks with specific spatial arrangement, but also a promising platform for investigating the aggregation behavior of fluorescent chromophores.

Automated summary

In this study, a series of double- and triple-decker supramolecular complexes were successfully constructed, achieving dye aggregates with specific spatial arrangements. The results of this study are important for the construction of multi-stacks and the investigation of aggregation behavior of fluorescent chromophores.