Journal
SMALL
Volume 18, Issue 16, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202200694
Keywords
diffusion barriers; heterostructures; plasma; sodium-ion batteries; titanium carbonitride; titanium dioxide
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Funding
- National Natural Science Foundation of China [62075100]
- Australian Research Council
- QUT Centre for Materials Science
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This study demonstrates substantially enhanced Na+ ion transport and charge transfer kinetics by constructing a non-rectifying titanium carbonitride/nitrogen-doped TiO2 heterostructure, leading to excellent electrochemical performance in lithium-ion batteries and sodium-ion batteries.
Anatase TiO2 is a promising anode material for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to its high specific capacity, low cost, and excellent cycle stability. However, low electrical conductivity and poor Na+ ion transport in TiO2 limit its practical applications. Here, substantially boosted Na+ ion transport and charge transfer kinetics are demonstrated by constructing a near-ideal non-rectifying titanium carbonitride/nitrogen-doped TiO2 (TiCxN1-x/N-TiO2) heterostructure. Owing to the fast plasma effects and metastable hybrid phases, the TiCxN1-x is epitaxially grown on TiO2. Energy band engineering at the interface induces high electron densities and a strong built-in electric field, which lowers the Na+ diffusion barrier by a factor of 1.7. As a result, the TiCxN1-x/N-TiO2 electrode exhibits excellent electrochemical performance. The reversible specific capacities at rates of 0.1 and 10 C reach 312.3 and 173.7 mAh g(-1), respectively. After 600 cycles of charge and discharge at 10 C, the capacity retention rate is 98.7%. This work discovers an effective non-equilibrium plasma-enabled process to construct heterointerfaces that can enhance Na+ ion transport and provides generic guidelines for the design of heterostructures for a broader range of energy storage, separation, and other devices that rely on controlled ionic transport.
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