Significantly Promoting the Photogenerated Charge Separation by Introducing an Oxygen Vacancy Regulation Strategy on the FeNiOOH Co-Catalyst

Semiconductor/co-catalyst coupling is considered as a promising strategy to enhance the photoelectrochemical (PEC) conversion efficiency. Unfortunately, this model system is faced with a serious interface recombination problem, which limits the further improvement of PEC performances. Here, a FeNiOOH co-catalyst with abundant oxygen vacancies on BiVO4 is fabricated through simple and economical NaBH4 reduction to accelerate hole transfer and achieve efficient electron-hole pair separation. The photocurrent of the BV (BiVO4)/Vo-FeNiOOH system is more than four times that of pure BV. Importantly, the charge transfer kinetics and charge carrier recombination process are studied by scanning photoelectrochemical microscopy and intensity modulated photocurrent spectroscopy in detail. In addition, the oxygen vacancy regulation proposed is also applied successfully to other semiconductors (Fe2O3), demonstrating the applicability of this strategy.

Automated summary

This study investigates the coupling of FeNiOOH co-catalyst with BiVO4 electrode to enhance the photoelectrochemical conversion efficiency. The co-catalyst fabrication with abundant oxygen vacancies accelerates hole transfer and achieves efficient electron-hole pair separation. The strategy demonstrates improved charge transfer kinetics and suppressed charge carrier recombination.