Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 133, Issue 34, Pages -Publisher
WILEY
DOI: 10.1002/app.43821
Keywords
composites; functionalization of polymers; graphene and fullerenes; mechanical properties; nanotubes
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Funding
- National Research Foundation of Korea - Ministry of Science, Information and Communications Technology, and Future Planning [2013M1A3A3A02042257]
- KOREATECH Research Grant for New Professors
- National Research Foundation of Korea [2013M1A3A3A02042257] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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In an attempt to enhance the mechanical properties of epoxy/graphene-based composites, the interface was engineered through the functionalization of graphene oxide (GO) sheets with p-phenylenediamine; this resulted in p-phenylenediamine functionalized graphene oxide (GO-pPDA). The morphology and chemical structure of the GO-pPDA sheets were studied by spectroscopic methods, thermal analysis, X-ray diffraction, and transmission electron microscopy. The characterization results show the successful covalent functionalization of GO sheets through the formation of amide bonds. In addition, p-phenylenediamine were polymerized on graphene sheets to form crystalline nanospheres; this resulted in a GO/poly(p-phenylenediamine) hybrid. The mechanical properties of the epoxy/GO-pPDA composite were assessed. Although the Young's modulus showed improvement, more significant improvements were observed in the strength, fracture strain, and plane-strain fracture toughness. These improvements were attributed to the unique microstructure and strong interface between GO-pPDA and the epoxy matrix. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43821.
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