Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 96, Issue 3, Pages 478-484Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024422030244
Keywords
thermodynamics; liquid-liquid; critical states
Categories
Funding
- Russian Science Foundation [21-13-00038]
- Russian Science Foundation [21-13-00038] Funding Source: Russian Science Foundation
Ask authors/readers for more resources
Thermodynamic relationships are used to analyze phase diagrams of systems with chemical interaction near critical points. New variables are introduced to represent mole fractions. A general equation is derived for the isothermal-isobaric curve of chemical equilibrium in generalized concentration variables. Analysis of chemically reacting liquid-liquid systems near critical points is conducted and corresponding diagrams are presented.
Thermodynamic relationships are obtained to analyze patterns in the phase diagrams of systems with chemical interaction between materials in the vicinity of critical points. The procedure is based on introducing new variables (analogs of mole fractions). A general equation is derived for the isothermal-isobaric curve of chemical equilibrium in generalized concentration variables. The behavior of chemically reacting liquid-liquid systems in the vicinity of the critical points of two-phase equilibria is analyzed, and the corresponding diagrams are presented.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available