4.2 Article

Electrochemical Catalytic Reduction of p-Nitrotoluene on the Surface of α-Ag2S Crystal

Journal

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 96, Issue 4, Pages 899-906

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S003602442204029X

Keywords

p-nitrotoluene; alpha-Ag2S crystal; catalytic reduction

Funding

  1. Open Science Foundation for Jiangsu Province Key Laboratory for Chemistry of Low-Dimentional Materials [JSKC17009]
  2. Open Science Foundation for Jiangsu Key Laboratory for Biomass-based Energy and Enzyme Technology [JSBEET1207]
  3. Science Foundation for Huaiyin Normal University [11HSGJBZ13]

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Alpha-Ag2S crystals were synthesized using hydrothermal method and characterized. The study found that alpha-Ag2S crystals can catalyze the reduction of p-nitrotoluene, and the reduction mechanism was discussed.
alpha-Ag2S crystals are synthesized using thioacetamide and silver nitrate using hydrothermal method, and the crystals are characterized by scanning electron microscopy, energy dispersive spectrometer, AC impedance spectrum and X-ray diffractometer. Electrochemical reduction of p-nitrotoluene at alpha-Ag2S crystal modified glassy carbon electrode is investigated, and the results indicating that the alpha-Ag2S can catalyze the reduction of p-nitrotoluene, and the reduction mechanism of p-nitrotoluene is also discussed.

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