4.8 Article

Integrative technical, economic, and environmental sustainability analysis for the development process of biomass-derived 2,5-furandicarboxylic acid

Journal

RENEWABLE & SUSTAINABLE ENERGY REVIEWS
Volume 157, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.rser.2021.112059

Keywords

Energy efficiency; Renewable; Heat pump; Terephthalic acid; Sustainability; Economics

Funding

  1. National Research Foundation of Korea (NRF) - Korean government [2021R1A4A3025742]
  2. C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2015M3D3A1A01064929]
  3. National Research Foundation of Korea [2021R1A4A3025742] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This study presents a new process design for economically producing FDCA from lignocellulosic biomass. The process maximizes the economics by introducing effective biomass fractionation method and minimizing energy consumption. The economic feasibility and environmental sustainability of the process were assessed through techno-economic analysis and life-cycle assessment.
The utilization of biomass, a bountiful and renewable natural resource, has become increasingly important with respect to climate change and environmental regulation. The conversion of lignocellulosic biomass to 2,5-furandicarboxylic acid (FDCA) is a particularly promising technology that is essential for polyethylene furanoate production, which can replace existing petroleum-derived terephthalic acid. This study presents a new process design for economic FDCA production from lignocellulosic biomass. The economics of the process are maximized by introducing an effective biomass fractionation method based on catalytic conversion and separation subsystems. Pinch analysis coupled with a heat pump was performed to minimize the utility consumption in the process, thereby reducing the heating requirement by 66.3%. Furthermore, the integrative economic feasibility and environmental sustainability of the process were systematically assessed via techno-economic analysis (TEA) and life-cycle assessment (LCA). The TEA determined a minimum FDCA selling price of $1,520/ton that can increase to $5,203/ton given cost growth and performance at the pioneer plant. Moreover, sensitivity analysis identified the principal cost drivers of the process. LCA showed the environmental impact of each subsystem of the process and revealed that exchanging fossil-based electricity sources for renewable sources and technology can lead to a more environmentally friendly process. Integrative process design can provide comprehensive perspectives for decision-makers.

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