Journal
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
Volume 119, Issue 23, Pages -Publisher
NATL ACAD SCIENCES
DOI: 10.1073/pnas.2120088119
Keywords
alloy catalysts; environmental TEM; WGSR; CuAu; surface activation
Categories
Funding
- National Natural Science Foundation of China [22172110, U20A20151]
- Haihe Laboratory of Sustainable Chemical Transformations
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Bimetallic alloy catalysts exhibit strong dependence on their activity, selectivity, and stability based on their structure and composition. In this study, atomic-scale synergetic surface activation of CuAu under a water-gas shift reaction condition was visualized using aberration-corrected environmental transmission electron microscopy. This research provides insights into the mechanism of alloy surface activation and catalysis of chemical reactions.
Bimetallic alloy catalysts show strong structural and compositional dependence on their activity, selectivity, and stability. Often referred to as the synergetic effect of two metal elements in the alloys, their detailed dynamic information, structurally and chemically, of catalyst surface under reaction conditions remains largely elusive. Here, using aberration-corrected environmental transmission electron microscopy, we visualize the atomic-scale synergetic surface activation of CuAu under a water-gas shift reaction condition. The unique periodic structural activation largely determines the dominating reaction pathway, which is related to a possible carboxyl reaction route corroborated by density functional theory-based calculation and ab initio molecular dynamics simulation. These results demonstrate how the alloy surface is activated and catalyzes the chemical reaction, which provides insights into catalyst design with atom precision.
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