4.8 Article

Nonaffine Strains Control Ductility of Metallic Glasses

Journal

PHYSICAL REVIEW LETTERS
Volume 128, Issue 15, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.128.155501

Keywords

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Funding

  1. U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division
  2. DOE Office of Science [DE-AC02-06CH11357]

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This study suggests that the plasticity of metallic glasses is related to the local atomic rearrangements under stress, rather than their atomic structure directly. By conducting experiments on various bulk metallic glasses, researchers found that the extent of local deviation from affine deformation within the elastic regime is strongly correlated with the plastic behavior of metallic glasses beyond yield.
The origin of limited plasticity in metallic glasses is elusive, with no apparent link to their atomic structure. We propose that the response of the glassy structure to applied stress, not the original structure itself, provides a gauge to predict the degree of plasticity. We carried out high-energy x-ray diffraction on various bulk metallic glasses (BMGs) under uniaxial compression within the elastic limit and evaluated the anisotropic pair distribution function. We show that the extent of local deviation from the affine (uniform) deformation in the elastic regime is strongly correlated with the plastic behavior of BMGs beyond yield, across chemical compositions and sample history. The results suggest that the propensity for collective local atomic rearrangements under stress promotes plasticity.

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