4.5 Article

Experimental study on the wax deposit properties in the crude oil pipeline: Crystal morphology, yield stress

Journal

PETROLEUM SCIENCE AND TECHNOLOGY
Volume 40, Issue 22, Pages 2737-2754

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/10916466.2022.2047067

Keywords

Crude oil pipeline; crystal morphology; microscopic observation; wax deposit; yield stress

Funding

  1. National Natural Science Foundation of China [51904147, 51804153]
  2. China Postdoctoral Science Foundation [2019M660176, 2019M662566]
  3. Doctoral Start-up Foundation of Liaoning Province [20180540044]
  4. Scientific Research Fund of Liaoning Provincial Education Department [L2020035, L2019033]

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This study quantitatively analyzed the radial properties of wax deposits in crude oil pipelines. It was found that the quantity and size of wax crystals in the deposits increased radially, while the aspect ratio and boundary fractal dimension varied little. Additionally, the yield stress of the wax deposits increased with higher wax content and longer deposition duration, with the bottom deposit showing a stronger structure and higher yield stress compared to the surface deposit.
Radial properties of wax deposits in crude oil pipeline are of great significance for the selection of wax removal process. Herein, the wax deposits were obtained in a flow loop device and the important characteristics of wax crystal morphology and yield stress were quantitatively analyzed. The polarizing microscopic observations revealed that the amount and size of wax crystals increased in the radial from deposit surface to bottom, while the aspect ratio and boundary fractal dimension varied little, ranging from 1.68-1.80 and 1.61-1.75, respectively. In addition, the yield stress of wax deposit was found to increase with the rise of wax content and deposition duration, ranging from 5310-16,400 Pa in the cold flow experiments and 7550-24,500 Pa in the hot flow experiments. Furthermore, the bottom deposit was stronger in structure and presented higher yield stress than the surface deposit. This work provides a whole understanding on the wax deposit properties in different radial positions and is of great help to the analysis of pig force and pig selection.

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