Journal
ORGANOMETALLICS
Volume 41, Issue 9, Pages 1063-1066Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.2c00126
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology
- Ministry of Education, Culture, Sports, Science and Technology Japan [JPMXP09A19UT0186]
- JST, ERATO [JPMJER2103]
Ask authors/readers for more resources
In this study, we report the oxidative addition reaction of a hydroborane ligand with two low-valent Ir(I) precursors to form Ir(III) hydride complexes with a bidentate boryl/phosphine ligand. One cationic iridium complex easily replaces a THE and 1,5-COD supporting ligand by hydrogenation, yielding a stable Ir(III) eta(6)-benzene complex. The coordination of arene sheds light on the possible poisoning effects of arenes in catalytic reactions.
We here report the oxidative addition of a hydroborane ligand to two low-valent Ir(I) precursors to furnish Ir(III) hydride complexes bearing a bidentate boryl/phosphine ligand. One cationic iridium complex easily displaces a THE and 1,5-COD supporting ligand by hydrogenation in benzene, to form a stable Ir(III) eta(6) -benzene complex. The arene coordination thus gives insight into possible poisoning by arenes in catalytic reactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available