4.8 Article

Synthesis of Allenyl-Bdan via Cu(I)-Catalyzed Borylation of Propargylgem-Dichlorides

Journal

ORGANIC LETTERS
Volume 24, Issue 14, Pages 2660-2664

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c00704

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Funding

  1. National Natural Science Foundation of China [21871240]
  2. Fundamental Research Funds for the Central Universities [WK2060000017]

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A copper-catalyzed borylation of propargyl dichlorides was developed, leading to the formation of chloro-substituted allenyl-Bdan products in good yields under mild reaction conditions. The utilities of these products were examined through various derivatizations.
A copper-catalyzed borylation of propargyl dichlorides was developed under mild reaction conditions. Thecorresponding chloro-substituted allenyl-Bdan products were obtained in good yields. The utilities of allenyl-Bdan products wereexamined by their diverse derivatizations.

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