4.6 Article

Synthesis of hydrophilic carbon nanotube sponge via post-growth thermal treatment

Journal

NANOTECHNOLOGY
Volume 33, Issue 24, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/1361-6528/ac5bb7

Keywords

carbon nanotube sponges; thermal functionalization; oxygen-containing functional groups; water purification; chromatography

Funding

  1. Italian Ministry of Education, University and Research (MIUR)
  2. VILLUM FONDEN through the Young Investigator Program [19130]

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Clean water is crucial for ecosystems, human life, and socio-economic development. However, climate change, pollution, and population growth may lead to water scarcity. Therefore, it is important to develop new materials and efficient methods for treating waste and contaminated water. A recent study discovered that by treating carbon nanotube sponges at mild temperatures, the sponges can become hydrophilic and effectively remove toxic contaminants dissolved in water.
Clean water is vital for healthy ecosystems, for human life and, in a broader sense, it is directly linked to our socio-economic development. Nevertheless, climate change, pollution and increasing world population will likely make clean water scarcer in the near future. Consequently, it becomes imperative to develop novel materials and more efficient ways of treating waste and contaminated water. Carbon nanotube (CNT) sponges, for example, are excellent in removing oleophilic contaminants; however, due to their super-hydrophobic nature, they are not as efficient when it comes to absorbing water-soluble substances. Here, by means of a scalable method consisting of simply treating CNT sponges at mild temperatures in air, we attach oxygen-containing functional groups to the CNT surface. The functionalized sponge becomes hydrophilic while preserving its micro- and macro-structure and can therefore be used to successfully remove toxic contaminants, such as pesticides, that are dissolved in water. This discovery expands the current range of applications of CNT sponges to those fields in which a hydrophilic character of the sponge is more suitable.

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