Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 334, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.micromeso.2022.111776
Keywords
UZM-5; Synthesis; Crystalline phase; Catalysis; Ammonia production
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Funding
- National Natural Science Foundation of China [21808215, 21721004]
- Dalian Institute of Chemical Physics, CAS [ZZBS201815, DICPI201903]
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Pure UZM-5 zeolite with nanosheet or rosette-shaped morphology was successfully synthesized by adjusting the synthesis parameters and incorporating trace ethanol in the reagent solution. The pure UZM-5 zeolite showed Lewis acid sites, making it a promising catalyst for electrocatalytic reduction of nitrate to ammonia.
Pure UZM-5 zeolite with either nanosheet or rosette-shaped morphology have been successfully synthesized by a charge density mismatch (CDM) method under a corresponding tumbling or static conditions. The synthesis parameters were fully investigated to abstain from commonly accompanying by-products, including SOD or amorphous phase which greatly interfered with the use of UZM-5. The crystalline phases and relative crystallinity of resultant products were carefully substantiated by using scanning electron microscope and X-ray diffraction. As a result, the molar ratios of water and structure directing agents thereof were deemed to be two vital parameters which had significant effects on the well-defined pure-phase UZM-5 zeolite production. Trace ethanol added in the reagent solution was found to play a role in zeolite purification. There is an urgent need in electrocatalytic reduction of nitrate to ammonia. In this work, pure UZM-5 zeolite with Lewis acid sites served as catalyst matrix for the application to produce this valuable chemical. Excellent ammonia production rate with high faradaic efficiency was achieved by using the obtained novel UZM-5-based catalyst for the reduction reaction, strongly proving the great potential of this young zeolite in catalysis applications.
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