Journal
MENDELEEV COMMUNICATIONS
Volume 32, Issue 2, Pages 253-255Publisher
ELSEVIER
DOI: 10.1016/j.mencom.2022.03.033
Keywords
Keywords; hydroxycarbonylation; palladium; olefins; carboxylic acids; formic acid; carbon monoxide
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A new protocol for Pd-catalyzed hydroxycarbonylation of olefins with formic acid under low pressure of CO has been developed. The reaction shows good selectivity towards 2-phenylpropionic acid in the carbonylation of styrene and linear acids in the carbonylation of terminal alkenes. The choice of catalyst precursor and solvent greatly affects the reaction.
A new protocol for Pd-catalyzed regioselective hydroxycarbonylation of olefins with formic acid under low pressure of carbon monoxide has been developed. The same catalytic system provides good selectivity to 2-phenylpropionic acid in carbonylation of styrene and to linear acids in carbonylation of terminal alkenes. The reaction is highly susceptible to catalyst precursor and solvent nature.
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