Journal
MENDELEEV COMMUNICATIONS
Volume 32, Issue 2, Pages 143-151Publisher
ELSEVIER
DOI: 10.1016/j.mencom.2022.03.001
Keywords
nanodiamonds; 3d; 4f-metals; chelate complexes; density functional theory; magnetochemistry; electron paramagnetic resonance
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Funding
- Russian Foundation for Basic Research [18-29-19038 Mk]
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This survey discusses recent achievements in the creation of a new type of material - nanodiamonds grafted with atoms of transition metals. It explores the structural features, scope, limitations, and potential applications of selected chelate complexes using density functional theory. Furthermore, the study investigates the location of copper ions relative to subsurface defects of detonation diamonds through the method of electron paramagnetic resonance (EPR).
This survey describes recent achievements in creating a new type of materials - nanodiamonds grafted with atoms of transition metals. Structural features of some selected chelate complexes studied by density functional theory, their scope and limitations as well as possible applications are discussed. Using the example of copper ions, their location relative to subsurface defects of detonation diamond is investigated by the method of electron paramagnetic resonance (EPR).
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