4.6 Article

Fabrication of polypyrrole enveloped reduced graphene oxide/iron oxide and determination of its photothermal properties

Journal

MATERIALS RESEARCH BULLETIN
Volume 150, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2022.111792

Keywords

Photothermal therapy; Near-infrared; Reduced graphene oxide; Iron oxide; Polypyrrole

Funding

  1. Scientific and Technological Research Council of Turkey (TUBITAK) [117M232]

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In this study, a polypyrrole enveloped reduced graphene oxide/iron oxide (rGO/Fe3O4@PPy) ternary nanocomposite was synthesized and its photothermal performance was tested. The results showed that the nanocomposite exhibited high photothermal efficiency and stability, making it a promising candidate for photothermal therapy practices.
Recently photothermal therapy has been viewed as an alternative to cancer treatment methods, fabrication of photosensitizing agents with high photothermal conversion efficiency has gained importance. In this study, polypyrrole enveloped reduced graphene oxide/iron oxide (rGO/Fe3O4@PPy) ternary nanocomposite was synthesized and its photothermal performance was put to test. Aqueous rGO/Fe3O4@PPy dispersions with 0.025-0.2 mg/mL concentrations were exposed to irradiation using a near-infrared laser at 1.5-3.0 W/cm(2) power densities, and the heating curves were obtained, which revealed that the agent can be used in hyperthermia treatments. Photothermal efficiency of the nanocomposite was found to be as high as 68.0%. Further-more, photothermal stability tests revealed that the nanocomposite can be used multiple times without a significant loss in obtained maximum temperature. The findings show that the design of the ternary nano-composite makes it an excellent candidate for photothermal therapy practices.

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