4.6 Article

Nanoflower shaped NiO/CeO2 p-n junction material for the degradation of pollutant under visible light

Journal

MATERIALS LETTERS
Volume 317, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2022.132122

Keywords

Photocatalyst; Semiconductor; p-n Junctions; Methyl orange; Oxidation

Funding

  1. King Saud University, Riyadh, Saudi Arabia [RSP2022R441]
  2. [ANID/FONDAP/15110019]

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This study reports the synthesis of flower-shaped p-n heterojunction NiO/CeO2 and investigates their properties and photocatalytic mechanism. The degradation efficiency of the synthesized catalysts for organic pollutant methyl orange (MO) is also discussed. The results show that this material exhibits outstanding activity and stability, making it a promising candidate for future applications.
The potential need of p-n junctions create an optimistic way of supporting photogenerated electron-hole pair separation and improving interfacial charge-transfer rates. In this context, a p-type semiconductor NiO can couple with n-type CeO2, thus approving visible light activity by forming p-n junctions. The visible light activity of two large band gap semiconductors still lacks some significant reasons. To solve this, for the first time, this paper reports 3D flower shaped p n heterojunction NiO/CeO2 synthesized via thermal decomposition method and studied their properties through various instrumental techniques. Besides, the photocatalytic mechanism of p n junction and the degrading efficiency of organic pollutant methyl orange (MO) for the synthesized catalysts was discussed. This achieves the outstanding activity and showed better stability which are useful for future applications.

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