4.6 Article

Hierarchical FeCo2O4@CoSe core-shell nanosheet arrays on nickel foam for high-performance supercapacitor

Journal

MATERIALS LETTERS
Volume 310, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2021.131458

Keywords

Composite materials; Electrodeposition; Supercapacitor; FeCo2O4

Funding

  1. National Natural Science Foundation of China [51877146]

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In this study, self-growing FeCo2O4@CoSe/NF layered core-shell composite materials were prepared using hydrothermal method and electrodeposition method. The CoSe shell effectively increased the conductivity of FeCo2O4 core, leading to synergistic effects that improved the overall electrochemical performance and stability of the material at high cycling numbers. The FeCo2O4@CoSe/NF exhibited a high specific capacity and capacity retention rate, while the assembled asymmetric capacitor (ASC) showed a high energy density under certain power densities.
Self-growing FeCo2O4@CoSe/NF layered core-shell composite materials on Ni foam (NF) were prepared by hydrothermal method and electrodeposition method. CoSe shell effectively increased the conductivity of FeCo2O4 core, and the synergistic effects of the two contents effectively improved the overall electrochemical performance. At a current density of 1A/g, FeCo2O4@CoSe/NF achieved a specific capacity of 724.2C/g and capacity retention rate of 94.1% after 5000 cycles. The assembled asymmetric capacitor (ASC) also achieved a high energy density of 57.19Wh/kg when the power density is 750 W/kg.

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