4.6 Article

Organic-Inorganic Hybrid Polysiloxane Brushes with Improved Lubrication and Load-Bearing Capacity

Journal

LANGMUIR
Volume 38, Issue 9, Pages 2832-2839

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.1c02937

Keywords

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Funding

  1. Key Research Program of the Chinese Academy of Sciences [XDPB24]
  2. National Natural Science Foundation of China [22032006, 22072169]
  3. NSAF [U2030201]
  4. Key Research Project of Shandong Provincial Natural Science Foundation [ZR2021ZD27, QYZDY-SSW-JSC013]
  5. Young Talents Support Plan of Gansu Association for Science and Technology [GXH2020626-14]

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In this study, a nanoscale organic-inorganic hybrid lubricative coating (OHL) with low friction coefficient and wear resistance was developed. By grafting polysiloxane brushes on an inorganic silica sol layer, the mechanical stability of the brushes was improved, and the lubrication performance was enhanced. The OHL coating demonstrated excellent stability and general applicability for reducing friction coefficient and enhancing wear resistance.
With the development of microelectromechanical systems (MEMS), ultrathin dry lubrication coatings have received significant attention. In this study, a nanoscale organic-inorganic hybrid lubricative coating (OHL) with a low friction coefficient and wear resistance was developed by grafting polysiloxane brushes on an inorganic silica sol layer. Friction evaluations, including the friction coefficient, load-bearing capacity, abrasion, and durability, were conducted. Compared with the surface of polysiloxane brushes without a silica sol layer, the introduction of a silica sol interlayer can effectively improve the mechanical stability of polysiloxane brushes; namely, the friction coefficient under high load pressure was able to remain low for a long time. In addition, the lubrication performance can also further improve by modifying the upper friction pair surface with the OHL. More importantly, the OHL has an excellent stability and general applicability. The OHL coating can be applied to various solid surfaces that provide a similar lubrication performance, which may provide a new vision for reducing the friction coefficient and enhancing the wear resistance, especially under dry friction conditions.

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