4.7 Article

Nacre-like alumina composites reinforced by zirconia particles

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 42, Issue 5, Pages 2319-2330

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2021.12.043

Keywords

Bio-inspiration; Nacre; Alumina; Zirconia; Field assisted sintering (FAST); Mechanical fracture properties; Composites

Funding

  1. Agence Nationale pour la Recherche [ANR-16-CE08-0006 BICUIT, DS0303-2016]
  2. Agence Nationale de la Recherche (ANR) [ANR-16-CE08-0006] Funding Source: Agence Nationale de la Recherche (ANR)

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In this study, the addition of zirconia particles was investigated to enhance the mechanical properties of nacre-like alumina ceramic composite. It was found that tetragonal zirconia improves the fracture resistance properties of the composite.
Nacre-like alumina is a class of bio-inspired ceramic composite manufactured by field-assisted sintering of green bodies made primarily of alumina platelets with an anisotropic microstructure. Here we investigate the addition of zirconia particles to enhance the mechanical properties of the composite. The resulting structure is a nacre-like anisotropic structure which features deflection and reinforcement during crack propagation. Monoclinic zirconia has no impact on the mechanical properties of the composite while tetragonal zirconia improves its fracture resistance properties. Both types of zirconia seem to slow down grain growth during sintering. The addition of zirconia stabilised in the tetragonal phase is thus a good option to obtain a composite with a fine microstructure and higher mechanical properties than a standard nacre-like alumina, with a flexural strength of 626 +/- 39 MPa and a crack initiation toughness of 6.1 +/- 0.6 MPa.m0.5.

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