4.7 Article

3D printing of NiZn ferrite architectures with high magnetic performance for efficient magnetic separation

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 42, Issue 4, Pages 1522-1529

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2021.11.052

Keywords

NiZn ferrite; 3D printing; Additive manufacturing; Magnetic properties; Magnetic separation

Funding

  1. Natural Science Foundation of Shandong Province [ZR2020QE040]
  2. National Key Research and Development Project [2020YFB1313604]
  3. Natural Science Foundation of Guangdong Province [2020A1515011547]
  4. Shenzhen Fundamental Research Project [JCYJ20190808144009478, 20200731211324001]

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In this study, NiZn ferrites with mesh structures were successfully fabricated by 3D printing accompanied by the solid-state reaction. The influence of compositions on the structural and magnetic properties of NiZn ferrites was investigated, and it was found that the saturation magnetization was significantly enhanced for NiZn ferrites with a zinc concentration of 0.4. The study also demonstrated the potential of using NiZn ferrites with intricate mesh structures for magnetic separation.
Magnetic materials with desired architectures and high performance have become increasingly important for applications. In this work, NiZn ferrites with mesh structures have been successfully fabricated from preliminary precursors by three-dimensional (3D) printing accompanied by the solid-state reaction. The influence of compositions on structural and magnetic properties of NiZn ferrites were systematically investigated. It was obvious that the saturation magnetization was significantly enhanced to 77 emu/g for NiZn ferrites with a zinc concentration of 0.4, which was a much higher value compared to Ni ferrites. This is attributed not only to the wellknown cationic distribution, but also to the grain growth with extraordinarily high crystallinity. Consequently, NiZn ferrites with intricate mesh structures were utilized for magnetic separation, and the distributions of magnetic flux density were simulated. Overall, the fabrication of NiZn ferrites by 3D printing is attractive for scaled-up applications, and also paves the promising avenue for magnetic separation.

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