Synthesis and Optimization of ZnMn2O4 Cathode Material for Zinc-Ion Battery by Citric Acid Sol-Gel Method

Review Chemistry, Multidisciplinary

Recent Developments and Challenges of Vanadium Oxides (VxOy) Cathodes for Aqueous Zinc-Ion Batteries

Tao Zhou et al.

Summary: This paper reviews the application of vanadium oxides as cathode materials in aqueous zinc ion batteries, discussing current issues, optimization strategies, and future research directions.

CHEMICAL RECORD (2022)

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Review Chemistry, Physical

Cathode materials for aqueous zinc-ion batteries: A mini review

Tao Zhou et al.

Summary: Despite the advantages of LIBs, ZIBs are attracting attention as a promising alternative due to their low cost, high safety, and high synergistic efficiency. However, current cathode materials for ZIBs have shortcomings, necessitating the search for materials to improve battery performance.

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Editorial Material Materials Science, Multidisciplinary

Achieving both high reversible and stable Zn anode by a practical glucose electrolyte additive toward high-performance Zn-ion batteries

Ming Song et al.

Summary: This study introduces a method of using glucose as an electrolyte additive to improve the performance of aqueous Zn-ion batteries, enabling the zinc anode to have higher reversibility and stability.

RARE METALS (2022)

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Article Chemistry, Multidisciplinary

New Insight on K2Zn2V10O28 as an Advanced Cathode for Rechargeable Aqueous Zinc-Ion Batteries

Tao Zhou et al.

Summary: Aqueous zinc-ion batteries (ZIBs) have attracted extensive attention due to their low cost and environmental compatibility. Finding suitable cathode materials remains a major challenge. Polyoxovanadates (POVs), a branch of polyoxometalates (POMs), are considered promising electrode materials for reversible aqueous ZIBs. This study reports the use of POVs (K2Zn2V10O28: KZVO) as an advanced cathode material for storing Zn2+, with high discharge capacity, considerable energy density and power density, and robust cyclic performance.

SMALL (2022)

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Review Chemistry, Multidisciplinary

Strategies for constructing manganese-based oxide electrode materials for aqueous rechargeable zinc-ion batteries

Ying Liu et al.

Summary: This article provides a comprehensive summary of recent advances in Mn-based compounds as electrode materials for zinc ion batteries, including the design strategies of electrode structures, optimization of electrochemical performance, and clarification of energy storage mechanisms. Aqueous zinc ion batteries have the advantages of environmental friendliness, low cost, and convenient operation.

CHINESE CHEMICAL LETTERS (2022)

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Review Materials Science, Ceramics

Recent developments in zinc-based two-cation oxide spinels: From synthesis to applications

N. A. Masmali et al.

Summary: The article discusses the properties and applications of zinc-based two-cation oxide spinel semiconductors, highlighting their unique optical and electrical characteristics, ability to undergo multiple redox reactions, and magnetic properties.

CERAMICS INTERNATIONAL (2021)

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Article Engineering, Environmental

Defect modulation of ZnMn2O4 nanotube arrays as high-rate and durable cathode for flexible quasi-solid-state zinc ion battery

Wenda Qiu et al.

Summary: The novel N-doping coupled oxygen vacancies modulated ZMO nanotube arrays (NTAs) exhibit excellent capacity, rate capability, and long-term durability as a high-performance cathode for rechargeable ZIBs.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Materials Science, Multidisciplinary

Crossroads in the renaissance of rechargeable aqueous zinc batteries

Junhua Song et al.

Summary: Aqueous zinc batteries are dominating the primary battery market with alkaline chemistries and are now being developed as rechargeable devices for grid-scale energy storage applications. Significant progress has been made in improving cyclability in alkaline, neutral, and mild acidic systems, with a focus on static closed cell designs in this review. Challenges and advancements in developing highly rechargeable alkaline and mild acidic batteries are examined, while flow batteries and open systems like zinc-air batteries are excluded due to space constraints.

MATERIALS TODAY (2021)

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Editorial Material Materials Science, Multidisciplinary

Electrolytes speed up development of zinc batteries

Chen-Xuan Xu et al.

RARE METALS (2021)

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Sn doped ZnMn2O4 microspheres with excellent electrochemical performance and high cycle stability

Chuansheng Chen et al.

Summary: Sn-doping ZnMn2O4 porous microspheres with shell structure can enhance electrochemical performance by increasing crystal plane spacing. A Sn doping content of 0.5% leads to the highest specific capacitance and improved cycle stability in the chargedischarge process.

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Article Chemistry, Multidisciplinary

In Situ Oriented Mn Deficient ZnMn2O4@C Nanoarchitecture for Durable Rechargeable Aqueous Zinc-Ion Batteries

Saiful Islam et al.

Summary: A novel Mn-deficient ZnMn2O4@C nanoarchitecture cathode material for rechargeable aqueous zinc-ion batteries has been developed, showing promising performance with high capacity retention and good electronic conductivity, indicating great potential for practical applications.

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Review Chemistry, Physical

Innovative zinc-based batteries

Niklas Borchers et al.

Summary: The demand for high-performance, affordable, and safe energy storage solutions is increasing, particularly with the incorporation of fluctuating electricity sources in the electric grid. Zinc batteries are considered particularly environmentally friendly due to their use of abundant raw materials and ease of recyclability, as well as their high energy densities.

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Review Chemistry, Applied

Recent advances in energy storage mechanism of aqueous zinc-ion batteries

Duo Chen et al.

Summary: Aqueous rechargeable zinc-ion batteries have been receiving increasing research interest due to their safety, cost competitiveness, and capacity advantages compared to lithium ion batteries. However, the disputed energy storage mechanism has been a hindrance to their development. This review provides a detailed summary of the energy storage mechanisms of ZIBs and proposes promising research directions.

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Article Chemistry, Physical

Honeycomb-like carbon with doping of a transition-metal and nitrogen for highly efficient zinc-air battery and zinc-ion battery

Qian Huang et al.

Summary: This study presents a novel method for preparing transition-metal/nitrogen co-doped honeycomb-like carbon materials using freeze-drying and one-step pyrolysis. The prepared materials function as cathode and anode materials for zinc-air and zinc-ion batteries, showing high performance and cycle stability.

SUSTAINABLE ENERGY & FUELS (2021)

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Article Materials Science, Multidisciplinary

Hollow-porous nanospheres of ZnMn2O4 spinel: A high energy density cathode for rechargeable aqueous battery

Atin Pramanik et al.

Summary: Well-controlled hollow-porous nanostructures, such as spinel ZnMn2O4, show enhanced charge storage capacity, but stable interface engineering of such structures with reversible faradaic reactions remains a challenge. ZMO(HS) as a faradaic electrode in alkaline electrolyte demonstrates high specific capacity, and a full cell RAB with ZMO(HS)//AC shows promising energy storage performance with long cycling stability.

MATERIALS CHEMISTRY AND PHYSICS (2021)

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Review Chemistry, Applied

Review of vanadium-based electrode materials for rechargeable aqueous zinc ion batteries

Ying Liu et al.

Summary: Vanadium-based compounds are considered suitable cathode candidates for ZIBs with various structures and large layer spacings. This review emphasizes on the electrode design strategy, electrochemical performances, and energy storage mechanisms while pointing out the limitations and future prospects of vanadium-based materials.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Review Chemistry, Applied

Recent advances and perspectives on vanadium- and manganese-based cathode materials for aqueous zinc ion batteries

Na Liu et al.

Summary: The growing demand for energy storage has prompted researchers to explore advanced batteries, with aqueous zinc ion batteries (ZIBs) emerging as a promising option. While rechargeable ZIBs offer high safety, low cost, environmental friendliness, and competitive performance, the development of suitable zinc ion intercalation-type cathode materials remains a challenge. Vanadium-based and manganese-based compounds are the most advanced and widely used rechargeable ZIBs electrodes.

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Review Chemistry, Physical

The strategies of boosting the performance of highly reversible zinc anodes in zinc-ion batteries: recent progress and future perspectives

Chenghan Zhao et al.

Summary: Rechargeable zinc-metal batteries have attracted attention as a potential substitute for lithium-ion batteries due to their low cost, large volumetric capacity, and safe aqueous electrolyte use. However, issues such as poor cycling durability and low coulombic efficiency of zinc anodes have hindered further development, with research focusing on addressing dendrite growth, surface passivation, and hydrogen evolution during plating/stripping processes.

SUSTAINABLE ENERGY & FUELS (2021)

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Latest Advances in High-Voltage and High-Energy-Density Aqueous Rechargeable Batteries

Xinhai Yuan et al.

Summary: Aqueous rechargeable batteries (ARBs) have gained attention for their low cost, safety, environmental friendliness, and easy manufacturing, but face challenges such as narrow electrochemical stability window of water, poor electrode material percolation, and low energy density. Recent pioneering work has been carried out to address these challenges and inspire further research for high-performance aqueous energy storage systems.

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Nickel and cobalt Co-substituted spinel ZnMn2O4@N-rGO for increased capacity and stability as a cathode material for rechargeable aqueous zinc-ion battery

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Porous cube-like Mn3O4@C as an advanced cathode for low-cost neutral zinc-ion battery

Hui Chen et al.

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In-situ probing phase evolution and electrochemical mechanism of ZnMn2O4 nanoparticles anchored on porous carbon polyhedrons in high-performance aqueous Zn-ion batteries

Cheng Yang et al.

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Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry

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Current status and future directions of multivalent metal-ion batteries

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The dominant role of Mn2+ additive on the electrochemical reaction in ZnMn2O4 cathode for aqueous zinc-ion batteries

Vaiyapuri Soundharrajan et al.

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Oxide-based cathode materials for rechargeable zinc ion batteries: Progresses and challenges

Yingze Zhou et al.

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Fundamentals and perspectives in developing zinc-ion battery electrolytes: a comprehensive review

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Revealing the correlation between structural evolution and Li+ diffusion kinetics of nickel-rich cathode materials in Li-ion batteries

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A Highly Reversible Zn Anode with Intrinsically Safe Organic Electrolyte for Long-Cycle-Life Batteries

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Advanced electrochemical performance of ZnMn2O4/N-doped graphene hybrid as cathode material for zinc ion battery

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Ultrafast Rechargeable Zinc Battery Based on High-Voltage Graphite Cathode and Stable Nonaqueous Electrolyte

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Highly Reversible and Rechargeable Safe Zn Batteries Based on a Triethyl Phosphate Electrolyte

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An innovation: Dendrite free quinone paired with ZnMn2O4 for zinc ion storage

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Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface

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Synthesis and Optimization of ZnMn2O4 Cathode Material for Zinc-Ion Battery by Citric Acid Sol-Gel Method

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