High-Throughput Screening of Rattling-Induced Ultralow Lattice Thermal Conductivity in Semiconductors

Thermoelectric (TE) materials with rattling model show ultralow lattice thermal conductivity for high-efficient energy conversion between heat and electricity. In this work, by analysis of the key spirit of the rattling model, we propose an efficient empirical descriptor to realize the high-throughput screening of ultralow thermal conductivity in a series of semiconductors. This descriptor extracts the structural information of rattling atoms whose bond lengths with all the nearest neighboring atoms are larger than the sum of corresponding covalent radiuses. We obtain 1171 candidates from the Materials Project (MP) Database that contains more than 100 000 materials. Combining the empirical equation of high-throughput computation with a machine learning algorithm, we compute the approximate lattice thermal conductivities (kappa L) and find the kappa(L) values of 532 materials are less than 2.0 W m(-1) K-1 at 300 K, which can be regarded as the criteria of ultralow kappa(L) in general. In particular, we demonstrate that halide double perovskites structures show ultralow kappa(L), which provides valuable references for promising low kappa(L) materials in future experiments. In order to further verify our computational results, we calculate accurate kappa(L) for Rb2SnBr6 and CsCu3O2 as candidates with the low lattice thermal conductivity by solving the phonon Boltzmann transport equation. In particular, we demonstrate that Rb2SnBr6 has the lowest kappa(L) value of 0.1 W m(-1) K-1 at 300 K of all known thermal conductivity materials with the rattling model so far.

Automated summary

In this study, we propose an efficient method to screen candidates with ultralow thermal conductivity in materials by analyzing the key spirit of the rattling model. Using a combination of structural information extraction and high-throughput computation, we identify 532 materials with ultralow thermal conductivity and verify the ultralow thermal conductivity of halide double perovskite structures.