Pyrolysis mechanism of holocellulose-based monosaccharides: The formation of hydroxyacetaldehyde

Fast pyrolysis of biomass will produce complex pyrolytic products. Hydroxyacetaldehyde (HAA) is one of the most important pyrolytic products, derived from fragmentation (ring scission) of holocelltilose. In this study, density functional theory (DFT) calculations are employed to reveal the HAA formation mechanisms from fast pyrolysis of four holocellulose-based monosaccharides, i.e., beta-D-glucopyranose, beta-D-mannopyranose, beta-D-xylopyranose and O-acetyl-beta-D-xylopyranose. Moreover, the theoretical calculation results of the beta-D-glucopyranose are confirmed by isotopic labeling fast pyrolysis experiments. The results indicate that during beta-D-glucopyranose pyrolysis, the HAA is mainly derived from C1-C2, C5-C6 and C3-C4. The C2-C3 bond is easy to break via retro-aldol reaction to form 1,2-ethenediol (ED) which will tautomerize into the HAA from C1-C2 with high selectivity, accounting for the largest proportion of total HAA. The second largest origin of the HAA is the C5-C6 segment in multiple pathways with low energy barriers. However, these reactions to form the HAA from C5-C6 are thermodynamically unfavorable, and moreover, there are facile competing reactions to produce other products. Importantly, the HAA and levoglucosan (LG) are mainly formed via competing parallel pyrolytic pathways. Only a little HAA will be derived from the secondary cracking of LG. In addition, the HAA formation mechanisms from beta-D-mannopyranose and beta-D-xylopyranose are similar as those from beta-D-glucopyranose. However, O-acetyl-beta-D-xylopyranose behaves differently from the other three monosaccharides due to the acetyl group at C2 position. The HAA will be mainly derived from C4-C5, accompanied with the formation of acetic acid (AA) from scission of the acetyl branch. (C) 2016 Elsevier B.V. All rights reserved.