4.6 Article

Facile synthesis of ultra-tensile hydrogels for flexible all-solid-state supercapacitor energy storage devices

Journal

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Volume 103, Issue 2, Pages 335-344

Publisher

SPRINGER
DOI: 10.1007/s10971-022-05833-w

Keywords

Borate ester; All-solid-state supercapacitor; Hydrogel; Polymer; Ultra-tensile

Funding

  1. National Natural Science Foundation of China [52173279, 52104301, 51873059, 22176053]
  2. Natural Science Foundation of Hunan Province, China [2021JJ40225, 2020JJ4336]
  3. Scientific Research Fund of Hunan Provincial Education Department, China [20A215, 20A220, 21A0409]

Ask authors/readers for more resources

In this paper, a super tensile hydrogel was prepared using a specific material, which can be used in flexible all-solid-state supercapacitors. The hydrogel has high specific capacitance and energy density, and it can maintain good electrochemical characteristics under different strains.
In this paper, poly3-acrylamidophenylboronic acid crosslinked acrylamide hydrogel (P(AAPBA-co-AM) gel) with super tensile characteristics was prepared by acrylamide polymerization using 3-aminophenylboric acid as the raw material, which was used in flexible all-solid-state supercapacitors. By altering the crosslinking density, the gel's tensile strength was optimized. It can be used as an ideal safe and non-toxic solid-state electrolyte for supercapacitors due to its ability to absorb aqueous electrolytes. The specific capacitance of the flexible supercapacitor is 116 F g(-1) and the energy density is 16.11 Wh kg(-1). Additionally, the gel created with a solvent content of 65% may withstand a 5000% strain under 170 kPa stress while retaining electrochemical characteristics at various bending angles. This gel has exceptional tensile deformability, making it suitable for supercapacitors with varying needs.

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