4.5 Article

Preparation and characterization of a high-efficiency radon adsorbing material based on activated carbon modified by water immersion and freeze-thaw

Journal

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 331, Issue 7, Pages 3125-3133

Publisher

SPRINGER
DOI: 10.1007/s10967-022-08345-7

Keywords

Activated carbon; Water immersion and freeze-thaw; Radon; Adsorption coefficient

Funding

  1. National Natural Science Foundation of China [11975120, 11875165]

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In this study, activated carbon was modified through water immersion and freeze-thaw cycles to enhance its radon adsorption capacity. The most effective modification involved three cycles of freezing at -80 degrees C and thawing at 50 degrees C, resulting in a 24% increase in radon adsorption coefficient. The modified activated carbon exhibited significant changes in morphology, with a significant increase in specific surface area of micropores, which was positively correlated with radon adsorption capacity.
In this paper, activated carbon has been modified by water immersion and freeze-thaw cycles to further improve its radon adsorption capacity. Under freezing at - 80 degrees C and thawing at 50 degrees C, three cycles of modification were most effective, the radon adsorption coefficient was increased by 24%, and remained stable after five repeated radon adsorption-desorption cycles. The apparent morphology of the modified activated carbon changed significantly. The specific surface area of micropores increased significantly and was positively correlated with the radon adsorption capacity. The new application of this method can provide some references for the modification of material. Graphical abstract Experimental flow process diagram. The activated carbon was modified by water immersion and freeze-thaw cycles under different experimental conditions, and the best modification process was determined by measuring the static adsorption coefficient. The activated carbon with better modification effect was characterized and tested to observe the morphological and structural changes. It was finally concluded that water immersion and freeze-thawing could effectively enhance the microporous volume, specific surface area and radon adsorption capacity of activated carbon. [GRAPHICS] .

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