4.8 Article

Stability of TMA-TEMPO-based aqueous electrolytes for redox-flow batteries

Journal

JOURNAL OF POWER SOURCES
Volume 525, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2022.230996

Keywords

Redox flow battery; Aminoxyl radical; Decomposition; Capacity fade rates; Electrolyte reactivation; Use-oriented cycling

Funding

  1. Thuringer Aufbaubank (TAB)
  2. European Social Fund (ESF)
  3. Thuringian Ministry of Economic Affairs, Science and Digital Society (TMWWdG) - state of Thuringia [2015 FGI 0021]
  4. EU

Ask authors/readers for more resources

This study investigates the fade rate of N,N,N-2,2,6,6-heptamethylpiperidinyloxy-4-ammonium chloride (TMA-TEMPO) in correlation with temperature and time through battery experiments. The main cause of capacity decay is the deactivation of the oxidized TMA-TEMPO. The results provide insights for the development of a use-oriented cycling program.
The TEMPO scaffold is one of the most prominent used posolyte systems in organic redox flow batteries (RFBs). While the aminoxyl radical is well known for his extraordinary stability, there are only a few studies investigating the stability of the respective oxoammonium cation. In this study, we utilize battery experiments to quantify the fade rate of the oxoammonium cation derived from N,N,N-2,2,6,6-heptamethylpiperidinyloxy-4-ammonium chloride (TMA-TEMPO) in correlation with temperature and time. The observed capacity decay is mostly caused by a deactivation of the oxidized TMA-TEMPO yielding the corresponding hydroxylamine, which can mostly be regenerated by reoxidation. Additionally, unbalanced compositionally symmetric flow cells are used to compare the fade rate at different temperatures combined with varying hold times showing a strong dependency on temperature and residence time in high states of charge. The acquired results are used for a use oriented cycling program comprising a single cycle per day. Furthermore, GC-HRMS and isotopic labeling are used to analyze the volatile decomposition products of heated and oxidized TMA-TEMPO, identifying key intermediates of the decomposition mechanism and the role of an aqueous environment.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available