Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 681, Issue -, Pages 561-570Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2016.04.200
Keywords
Green synthesis; Tin oxide; Nanoparticles; Aspalathus linearis extract; Photocatalytic response
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Funding
- National Research Foundation of South Africa (NRF) [NRF 2015-U2ACN2]
- French Centre National pour la Recherche Scientifique, iThemba LABS (NANOAFNET)
- UNESCO-UNISA Africa Chair in Nanosciences Nanotechnology [U2ACN2 2015]
- Organization for Women in Science for the Developing World [OWSDW 2015-U2ACN2]
- Abdus Salam ICTP via the Nanosciences African Network (NANOAFNET)
- African Laser Centre (ALC) [ALC 2015-U2ACN2]
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This contribution reports on the synthesis and the main physical properties of n-type SnO2 nanoparticles synthesized for the first time by a completely green chemistry process using Aspalathus linearis's natural extract as an effective chelating agent. Their surface/interface and volume properties by X-rays diffraction, Raman, X-rays photoemission & photoluminescence spectroscopies are reported. Their average diameter ranging from 2.1 to 19.3 nm follows a thermal governed equation of < empty setparticles > = 1.048 10(-5) T-2 - 4.92 10(-3) T + 2.84. The smallest SnO2 nanoparticles exhibit effective photocatalytic responses to Methylene blue, Congo red and Eosin Y. (C) 2016 Elsevier B.V. All rights reserved.
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