Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 8, Pages 5442-5450Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c00251
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Funding
- Science and Engineering Research Board (SERB), Government of India [SRG/2021/000834]
- MHRD
- IISER-TVM (for Institute fellowship)
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This study presents a novel method for the visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides, through synergistic halogen atom transfer (XAT) and nickel catalysis.
We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and tolerates avariety of functional groups affording C(sp3)-C(sp2) cross-coupling products in good to moderate yields
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