4.7 Article

SnO2/super P nanocomposites as anode materials for Na-ion batteries with enhanced electrochemical performance

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 658, Issue -, Pages 234-240

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.10.212

Keywords

SnO2; Super P; Nanocomposite; Na-ion battery; Anode

Funding

  1. National Key Technology RD Program [2013BAF09B02]
  2. National Natural Science Foundation of China [51472152]
  3. Innovation Team Assistance Foundation of Shaanxi Province [2013KCT-06]
  4. Scientific Special Foundation of Shaanxi Province Office of Education [15JK1074]
  5. Doctoral Initial Foundation [BJ14-16]
  6. 973 Special Preliminary Study Plan [2014CB260411]
  7. Graduate Innovation Fund of Shaanxi University of Science and Technology

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Super P was firstly used to enhance the electrochemical performance of SnO2 as anode in Na-ion battery. This composite was prepared by a simple hydrothermal method, exhibiting uniformly dispersed SnO2 nanoparticles on the super P carbon spheres. The SnO2/C nanocomposite could deliver a discharge capacity of 293 mAh g(-1) after 100 cycles at a current density of 50 mA g(-1). Even at 1000 mA g(-1), a capacity of 150 mAh g(-1) was still maintained. Further study found that SnO2/super P nanocomposite provided a high Na ion diffusion coefficient and good structural stability during the cycling test. Combining the advantages of low cost and environmental benignity suggest the SnO2/super P composites in this work have great potential as a promising anode for high performance Na-ion battery. (C) 2015 Elsevier B.V. All rights reserved.

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