Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1257, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2022.132628
Keywords
Quaternary phosphonium salt; Phase-transfer catalysis; Ionic liquid; Organocatalyst; Enantioselective reaction
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This review summarizes the important advances in the properties, synthesis, and applications of quaternary phosphonium salts as catalysts in chemical transformations and synthetic chemistry. It also discusses the applications of asymmetric phosphonium salts in enantioselective organic reactions in phase-transfer catalysis.
Progress a chemical reaction through catalysis is a privileged approach that includes almost 95% (in volume) of all of the usual chemical compounds. Therefore investigation about high efficient catalysts is an attractive and very prosperous research area. In this regard, quaternary phosphonium salts have gained considerable attention as catalysts in many chemical transformations and synthetic chemistry. In this review, recently important advances on the properties, synthesis, and applications of quaternary phosphonium salts in both homogeneous and heterogeneous catalysis forms are summarized. We also discussed the asymmetric phosphonium salts in a wide range of applications in phase-transfer catalysis into enantioselective organic reaction.(c) 2022 Published by Elsevier B.V.
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