Journal
JOURNAL OF MEMBRANE SCIENCE
Volume 643, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.memsci.2021.120049
Keywords
Mixture adsorption; Permeation selectivity; Microporous membrane; Surface potential; Permeabilities
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The study investigates the inter-relationship between characteristics of unary, binary, and ternary mixtures across microporous zeolite membranes through simulations. It shows that adsorption selectivity, diffusion selectivity, and permeation selectivity are practically the same for binary and ternary mixtures, indicating unique dependencies on the surface potential Phi. The component permeabilities in binary and ternary mixtures were found to be independent of partners and similar to unary permeabilities when compared at the same Phi.
The primary objective of this article is to investigate the possibility of inter-relating the characteristics of unary, binary, and ternary mixtures across microporous zeolite membranes. Towards this end, we performed Configurational-Bias Monte Carlo (CBMC) simulations of mixture adsorption equilibrium, and Molecular Dynamics (MD) simulations of guest diffusivities in unary (CO2, CH4, N-2, and H-2), binary (CO2/CH4, CO2/N-2, CH4/N-2, CO2/H-2), and ternary (CO2/CH4/N-2, CO2/CH4/H-2, CO2/N-2/H-2) mixtures in four zeolites: CHA, DDR, MFI, and FAU. The combined CBMC and MD data are used to obtain fundamental insights into the adsorption, diffusion, and permeation characteristics of the variety of guest/host combinations. Application of the Myers-Prausnitz theory shows that the adsorption selectivity for the i-j pair, S-ads,S-ij, in ternary mixtures has practically the same value as for the binary i-j mixture, provided the comparison is made as the same surface potential Phi, a convenient and practical proxy for the spreading pressure pi, that is calculable on the basis of the data on the unary isotherms of the constituent guests. For the mixtures investigated, departures from thermodynamic idealities do not cause deviations from the uniqueness of the S-ads,S-ij vs Phi dependence because the ratios of the activity coefficients gamma(i)/gamma(j) also appear to uniquely depend on Phi. The surface potential Phi is also the thermodynamically correct metric to describe the loading dependence of diffusivities. Compared at the same Phi, the diffusion selectivity for the i-j pair, S-diff,S-ij, in ternary mixtures has practically the same value as for the binary i-j mixture. Consequently, the permeation selectivity, S-perm,S-ij = S-ads,S-ij x S-diff,S-ij is also uniquely dependent on Phi. When compared at the same Phi, the component permeabilities, Pi(i) for CO2, CH4, and N-2 are found to be independent of the partners in the binary and ternary mixtures investigated and have practically the same as the values for the corresponding unary permeabilities.
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