Journal
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
Volume 33, Issue 31, Pages 23964-23973Publisher
SPRINGER
DOI: 10.1007/s10854-022-08074-3
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- Ministry of Science and Technology, Department of Science and Technology India [IF170759]
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The liquid exfoliation method was used to prepare MoSe2 nanosheets on silicon substrates, and the vibrational characteristics of MoSe2 nanosheets were investigated using Raman measurements. The results showed that increasing temperature caused a redshift in Raman modes and non-linear temperature dependence was observed. Analytical results indicated that three- and four-phonon anharmonic effects were responsible for the non-linear temperature dependence of Raman modes.
The liquid exfoliation method is employed to prepare MoSe2 nanosheets onto silicon (Si) substrates. The vibrational characteristics of MoSe2 nanosheets are elucidated by performing the Raman measurements over the temperature range from 81 to 300 K with a 473 nm laser. The formation of a few monolayer MoSe2 nanosheets is confirmed by XRD, TEM, and XPS before proceeding for temperature-dependent Raman studies. Our experimental investigations demonstrate that the proliferation in temperature brings about a redshift in A(1g) (out-of-plane) and E-2g(1) (in-plane) Raman modes. The obtained values of the first-order temperature coefficients for A(1g) and E-2g(1) modes are - 0.05279 +/- 0.00606 cm(-1) K-1 and - 0.07069 +/- 0.00769 cm(-1) K-1, respectively. We also observed that the Raman shift for both A(1g) and E-2g(1) modes has non-linear temperature dependence. To gain a better perspective regarding the observed nonlinear dependence, a physical model is invoked. Our analytical results indicate that three- and four- phonon anharmonic effects are responsible for the non-linear temperature dependence of Raman modes.
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