Synthesis and Theoretical Study of New Guanylated Cyclophosphazenes and Their Use in the CO2 Fixation into Styrene Carbonate

Three new guanylated cyclophosphazenes G1-G3 have been synthesized through the catalytic guanylation of three different bi, tetra and hexa (p-aminophenoxy)-cyclophosphazenes by using N,N'-diisopropylcarbodiimide as guanylating agent, ZnEt2 as catalyst and dry tetrahydrofuran as solvent. The resulting products have been characterized by H-1, C-13{H-1} and P-31{H-1} NMR spectroscopy. The hexaguanylated cyclophosphazenes exhibit a deep purple colour, unusual for this type of compounds. The electronic structure of these compounds was investigated by carrying out density functional calculations at PBE-D3(BJ)/TZP level of theory. The molecular structural analysis reveals that aromatic rings are stacked and time dependent density functional calculations show that a charge transfer electronic transition occurs between the aromatic rings which absorb light around 500-700 nm. Finally, the catalytic usefulness of guanylated cyclophosphazene compounds G1-G3 has been proven by the preparation of styrene carbonate from the reaction between styrene oxide and carbon dioxide.

Automated summary

Three new guanylated cyclophosphazenes were synthesized through catalytic guanylation of different cyclophosphazenes. The resulting compounds were characterized by NMR spectroscopy and their electronic structures were investigated. These compounds exhibit a deep purple color and show charge transfer electronic transitions between aromatic rings.