4.4 Article

Coupling Adsorption-Photocatalytic Degradation of Methylene Blue and Maxilon Red

Journal

JOURNAL OF FLUORESCENCE
Volume 32, Issue 4, Pages 1381-1388

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10895-022-02934-1

Keywords

Methylene blue; Maxilon red; Coupling adsorption-photodegradation; Rice straw; TiO2

Funding

  1. Science, Technology & Innovation Funding Authority (STDF)

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This study investigated the removal of MB and MR using adsorption and photodegradation mechanisms. Sequential operation of adsorption and photocatalytic degradation over TiO2 under visible light irradiation enhanced the removal efficiency. The results showed that TiO2 had good capacity for removing MB and MR dyes.
The MB and MR removal process by two mechanisms of adsorption using rice straw (absence of UV light) and photodegradation on TiO2 surfaces was investigated. MB and MR removal efficiency were further intensified upon the sequential operation of adsorption followed by photocatalytic degradation over TiO2 under visible light irradiation. The TiO2 was used to remove methylene blue (MB) and Maxilon Red (MR) dye from aqueous media by continuous mode at 25 +/- 2 degrees C, at pH 6.8 +/- 0.2. Photo-illumination study revealed 75.81 and 65.51% MB and MR removal with the dose of 1 g/L TiO2 with an initial concentration of 5 mg/L within 120 min. This study can be deemed of potential applications for the removal of MB and MR dyes on an industrial level using the synergistic adsorption-photocatalytic oxidation approach. A probable photodegradation mechanism was proposed.

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