Journal
JOURNAL OF ELECTRONIC MATERIALS
Volume 51, Issue 7, Pages 3391-3417Publisher
SPRINGER
DOI: 10.1007/s11664-022-09662-z
Keywords
Transition metal oxides; nanostructure; lithium-ion batteries
Categories
Funding
- National Science Foundation of China [21373074, 61675061]
- Key R & D projects in Anhui Province [202004a05020053]
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Lithium-ion batteries have been widely used in portable electric equipment due to their high energy density and long cycle life. However, the development of new electrode materials is crucial to overcome the limitations of commercial graphite. Transition metal oxides (TMOs) have emerged as promising electrode materials for their low cost and higher specific capacities. Nevertheless, TMOs face challenges such as low electrical conductivity, poor ionic conductivity, large volume expansion, and poor capacity retention. Various approaches, including the use of nanostructured materials and dispersing metal oxide nanoparticles in conductive mediums, have been employed to address these issues.
Lithium-ion batteries (LIBs) have been broadly utilized in the field of portable electric equipment because of their incredible energy density and long cycling life. In order to overcome the capacity and rate bottlenecks of commercial graphite and further enhance the electrochemical performance of LIBs, it is vital to develop new electrode materials. Transition metal oxides (TMOs) have emerged as a key type of electrode material for energy storage and conversion application for their low cost, rich abundance and higher specific capacities. However, these materials have low electrical conductivity, poor ionic conductivity and ion diffusion kinetics, large volume expansion, high-voltage hysteresis, and comprehensive structural reorganization that cause poor retention in capacity. Several approaches have been employed to overcome these issues such as preparing nanostructured materials and dispersing metal oxide nanoparticles in a conductive medium such as carbon, reduced graphene oxide, and carbon nanotubes (CNT), which can reduce volume expansion, provide shorter diffusion path length and enhance the contact area. This work briefly introduces the recent progress in TMO-based nanostructure composites as electrode materials for LIBs, and some relevant prospects are also proposed. [GRAPHICS] .
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