Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 910, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2022.116172
Keywords
Benzoquinone; Hydroquinone; Weak acid; Weak base; Aprotic solvent; pK(a)
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In this study, a method to determine the conjugate acid-base dissociation constants of weak acids and bases in aprotic solvents was found. By measuring the new peak potentials, which were independent of the concentration of hydroquinone and quinone, the dissociation constants can be accurately obtained.
The pK(a) and pK(b) of Bronsted-Lowry weak acids and weak bases in aprotic solvents are difficult to accurately determine. Herein, we found that in an aprotic solvent, the conjugate base of weak acid can produce a new, unambiguous anodic peak of hydroquinone, and the conjugate acid of weak base can produce a new cathodic peak of p-benzoquinone. These new peaks were due to the drastic change in pH near the electrode surface, and their potentials depended on the strength of conjugate acids and bases but not on the concentration of hydroquinone and quinone. Therefore, the conjugate acid-base dissociation constant can be measured by the new peak potential. Then, the weak acid-base dissociation constant can be obtained by the difference between the autoprotolysis constant of the aprotic solvent and the conjugate acid-base dissociation constant. The experimental results were consistent with those in literature.
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