Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 613, Issue -, Pages 349-357Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2022.01.044
Keywords
Sulfur-modified NiMoO4 nanorods; NiFe-layered double hydroxide; Core-shell nanostructure; Hydrogen evolution reaction; Oxygen evolution reaction; Seawater-splitting
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Funding
- Natural Science Foundation of Shandong Province, China [ZR2019MB062, ZR2014JL013]
- Key Research and Development Program of Shandong Province [2017GGX20143]
- Taishan Scholar Program of Shandong Province of China [ts201712045]
- Foundation of Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, QUST [SATM201603]
- foundation of Key Laboratory of Colloid and Interface Chemistry (Shandong University), Ministry of Education [201702]
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This study develops an efficient and abundant electrocatalyst for electrochemical seawater-splitting, which exhibits outstanding bifunctional catalytic activity in alkaline seawater and natural seawater electrolytes, making it a promising candidate for realistic seawater electrolysis.
Developing high-efficiency and earth-abundant electrocatalysts for electrochemical seawater-splitting is of great significance but remains a grand challenge due to the presence of high-concentration chloride. This work presents the synthesis of a three-dimensional core-shell nanostructure with an amorphous and crystalline NiFe-layered double hydroxide (NiFe-LDH) layer on sulfur-modified nickel molybdate nanorods supported by porous Ni foam (S-NiMoO4@NiFe-LDH/NF) through hydrothermal and electrodeposition. Benefiting from high intrinsic activity, plentiful active sites, and accelerated electron transfer, S-NiMoO4@NiFe-LDH/NIF displays an outstanding bifunctional catalytic activity toward oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in both simulated alkaline seawater and natural seawater electrolytes. To reach a current density of 100 mA cm(-2), this catalyst only requires overpotentials of 273 and 315 mV for OER and 170 and 220 mV for HER in 1 M KOH + 0.5 M NaCl freshwater and 1 M KOH + seawater electrolytes, respectively. Using S-NiMoO4@NiFe-LDH as both anode and cathode, the electrolyzer shows superb overall seawater-splitting activity, and respectively needs low voltages of 1.68 and 1.73 V to achieve a current density of 100 mA cm(-2) in simulated alkaline seawater and alkaline natural seawater electrolytes with good Cl resistance and satisfactory durability. The electrolyzer outperforms the benchmark IrO2 parallel to Pt/C pair and many other reported bifunctional catalysts and exhibits great potential for realistic seawater electrolysis. (C) 2022 Elsevier Inc. All rights reserved.
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