Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 610, Issue -, Pages 334-346Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.11.187
Keywords
Biomass; Organic Pollutants; Hexavalent Chromium; Heterogeneous Catalysis; Fe N doped Biochar
Categories
Funding
- National Natural Science Foundation of China [21876039]
- Australian Research Council [DP190103548]
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Fe-N@BC composites with Fe and N atoms dispersed on 3D hierarchically porous biochar were synthesized as an efficient catalyst for organic pollutant removal and CrVI reduction. The catalyst showed excellent activity due to high dispersion of Fe species, nitrogen doping, and hierarchical micro-mesopores, enabling exposure of more active sites for catalysis.
Fe, N atoms deposited on porous biochar (Fe-N@BC) composites were synthesized and employed as an efficient catalyst for organic pollutant removal and CrVI reduction. Naturally abundant, renewable and N-rich pomelo peel as a carbon and nitrogen source and unsubstituted phthalocyanine/iron phthalocyanine complexes as a Fe and nitrogen resource were used to develop the Fe-N@BC via a carbonization process. It is found that Fe-N@BC hybrids have homogeneous dispersion of Fe and N atoms on 3D hierarchically porous biochar, which significantly improves the performance toward the detoxification of organic pollutants using peroxymonosulfate as an oxidant, as well as the reduction of hexavalent chromium by formic acid as a reductant. Furthermore, the effects of Fe loading and pyrolytic temperature on catalysis were comprehensively analyzed and optimized. The excellent activity of Fe-N@BC in acid media can be attributed to the high dispersion of Fe species, high content of doped nitrogen as well as hierarchical micro-mesopores, which induce to expose more active sites for catalysis. Owing to the structureenabled acidic stability, Fe-N@BC efficiently retains its activity as well as its structural stability after several cycles of reactions. This work provides a new approach to construct Fe, N-doped biochar as an effective catalyst for the detoxification of organic and inorganic pollutants. (c) 2021 Elsevier Inc. All rights reserved.
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