4.5 Article

Electrolysis of glycerol to value-added chemicals in alkaline media

Related references

Note: Only part of the references are listed.
Review Engineering, Chemical

A review of recent progress on electrocatalysts toward efficient glycerol electrooxidation

Peter Adeniyi Alaba et al.

Summary: This review summarizes suitable, sustainable, and inexpensive alternative electrocatalysts to enhance the economic viability of glycerol electrooxidation process; the importance of prospective heteroatom-doped materials and their rational design is discussed; these findings provide insights for further efficient and cost-effective conversion of glycerol into value-added chemicals in future research and engineering applications.

REVIEWS IN CHEMICAL ENGINEERING (2021)

Article Thermodynamics

Fuel cell application in the automotive industry and future perspective

A. G. Olabi et al.

Summary: The automotive industry is a significant contributor to global emissions due to its high dependency on fossil fuels. This review discusses the current state, technological advances, and future prospects of fuel cells in the automotive industry, while also addressing factors impeding their advancement and potential solutions. The investigation aims to explore pragmatic approaches to reduce the overall cost of fuel cells and integrate them into the automotive industry.

ENERGY (2021)

Article Chemistry, Multidisciplinary

Direct and Indirect Electrooxidation of Glycerol to Value-Added Products

Michael Guschakowski et al.

Summary: This study investigated and compared different approaches for the direct and indirect electrooxidation of glycerol, a by-product of oleochemistry and biodiesel production, for the synthesis of value-added products and of intermediates for biofuel/electrofuel production. The different approaches were discussed regarding selectivity, conversion, and coulombic efficiency of the electrochemical glycerol oxidation.

CHEMSUSCHEM (2021)

Article Chemistry, Physical

Influence of Pd and Au on electrochemical valorization of glycerol over Ni-rich surfaces

Mohamed S. E. Houache et al.

Summary: In this study, bimetallic Pd@Ni and Au@Ni core-shell nanoparticles were synthesized for glycerol electrooxidation reaction in alkaline media. The addition of Pd and Au to Ni nanoparticles improved catalytic activity and selectivity for glycerate formation. DFT calculations suggested that the addition of Pd or Au to Ni NPs enhances OH adsorption and GEOR intermediates removal by reducing the work function of the nanoparticles.

JOURNAL OF CATALYSIS (2021)

Article Electrochemistry

Electro-Oxidation of Glycerol into Formic Acid by Nickel-Copper Electrocatalysts

Jiali Zhang et al.

Summary: In this study, non-precious metallic nickel-copper electrocatalysts were synthesized for the oxidation of glycerol in alkaline electrolytes. The catalysts' structural features were characterized and their electrochemical activity and product selectivity were investigated, with the Cu1Ni1@ACF catalyst showing the highest selectivity of 97.4% for formic acid.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Electrochemistry

Electrocatalytic Oxidation of Glycerol Using Solid-State Synthesised Nickel Boride: Impact of Key Electrolysis Parameters on Product Selectivity

Ann Cathrin Brix et al.

Summary: The study demonstrates a facile solid-state synthesis method to obtain Ni-boride catalysts for electrocatalytic glycerol oxidation reaction (GOR), which can produce valuable products like lactic acid by optimizing electrolyte composition and applied potential. Highly crystalline, mixed-phase Ni borides were successfully synthesized and showed enhanced GOR activity.

CHEMELECTROCHEM (2021)

Article Nanoscience & Nanotechnology

Modification of Nickel Surfaces by Bismuth: Effect on Electrochemical Activity and Selectivity toward Glycerol

Mohamed S. E. Houache et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Materials Science, Multidisciplinary

Increased electron transfer kinetics and thermally treated graphite stability through improved tunneling paths

O. Charles Nwamba et al.

JOURNAL OF MATERIALS SCIENCE (2020)

Review Chemistry, Multidisciplinary

Selective Electrooxidation of Glycerol Into Value-Added Chemicals: A Short Overview

Christophe Coutanceau et al.

FRONTIERS IN CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Two-Step Purification of Glycerol as a Value Added by Product From the Biodiesel Production Process

Abdul Aziz Abdul Raman et al.

FRONTIERS IN CHEMISTRY (2019)

Article Chemistry, Physical

Electrochemical modification of nickel surfaces for efficient glycerol electrooxidation

Mohamed S. E. Houache et al.

JOURNAL OF POWER SOURCES (2018)

Article Electrochemistry

Single Step Synthesis of Porous NiCoO2 for Effective Electrooxidation of Glycerol in Alkaline Medium

Anchu Ashok et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

Article Chemistry, Physical

Nickel-palladium electrocatalysts for methanol, ethanol, and glycerol oxidation reactions

Leandro L. Carvalho et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

Review Green & Sustainable Science & Technology

Glycerol production and its applications as a raw material: A review

H. W. Tan et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2013)

Article Electrochemistry

Hydrous Nickel Oxide: Redox Switching and the Oxygen Evolution Reaction in Aqueous Alkaline Solution

M. E. G. Lyons et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2012)

Review Chemistry, Multidisciplinary

Selective catalytic oxidation of glycerol: perspectives for high value chemicals

Benjamin Katryniok et al.

GREEN CHEMISTRY (2011)