Transamidation-based vitrimers from renewable sources

Vitrimers are polymeric materials that behave as thermosets at room temperature but, when heated, they exhibit a plastic flow similar to thermoplastics, enabling their reprocessability. A series of new bio-based polyamide-polyamine vitrimers are synthetized starting from tris(2-aminoethyl)amine and epoxidized methyl oleate, a material that can be easily prepared from renewable resources obtainable both from natural products and waste. The incorporation of free amine groups in the network enables the transamidation exchange reaction with the crosslinking amide functions; this reaction, if appropriately catalyzed, donates a full reprocessability to the material. Boric acid, which is known to be a green, cheap and non-toxic catalyst for transamidation reactions, is employed in this work. Once that the optimal condition for the transamidation reaction is found, different catalyst loadings are tested and the obtained materials are subjected to thermal and mechanical characterization. The obtained materials possess good thermal stability up to 300 degrees C and a T-g value ranging between 7 and 21 degrees C depending on the B(OH)(3) content. Furthermore it is possible to observe how the introduction of boric acid in the materials reduces the E-a (inferred from stress-relaxation experiments) of the transamidation reaction from 130 +/- 8 KJ mol(-1) to a mean value of 63 +/- 4 KJ mol(-1).

Automated summary

Vitrimers are innovative polymeric materials with the characteristics of thermosets at room temperature and plastics when heated. The use of bio-based polyamide-polyamine vitrimers prepared from renewable resources allows for reprocessability through transamidation exchange reaction, which can be catalyzed by boric acid. The incorporation of boric acid reduces the activation energy of the transamidation reaction and improves the thermal stability of the materials.