Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 900, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.163502
Keywords
Asymmetric supercapacitor; Mixed structure; Hydrothermal method; NiMoO4; CoMoO4
Categories
Funding
- National Natural Science Foundation of China [51872140, 51972173]
- program for Science and Technology Innovative Research Team in Universities of Jiangsu Province, Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
- `333 program' of Jiangsu Province, China [BRA2019262]
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In this research, Ni(Co)MoO4 hybrid materials with nanoneedle and nanosheet structure were successfully prepared on nickel foam by the hydrothermal method for high-stability supercapacitors. The presence of Co was found to increase the growth of nanoneedles on the surface of NiMoO4/NF, leading to improved cycling performance and capacitance retention. By controlling the molar ratio of Co, better electrochemical performance was achieved, resulting in a high energy density and power density in the asymmetric supercapacitor device. The good performance of the hybrid electrode is attributed to the mutual doping of Ni and Co with a mixed morphology.
In this work, the Ni(Co)MoO4 (NMO-Co) hybrid materials with nanoneedle and nanosheet structure were prepared on nickel foam (NF) by the hydrothermal method for high-stability supercapacitors. The effect of Co presence on the structure and electrochemical properties of NMO-Co was investigated. As the molar of Cobalt increased, more nanoneedles grew on the surface of NiMoO4/NF. The combination of the Ni-doped CoMoO4 nanoneedles and Co-doped NiMoO4 nanosheets was irregularly arranged on the surface of NF, which emerged an improvement of the cycling performance. When the molar ratio of Co: Ni: Mo was 0.5: 1: 1, the capacitance retention of the hybrid electrode was 80.1% after 10,000 cycles at 10 A g-1, while the pure NiMoO4 electrode was 53.1%. Moreover, an asymmetric supercapacitor device displayed high energy density and power density. The maximum energy density and power density could reach 55.71 Wh kg-1 and 14,999 W kg-1, respectively. The hybrid electrode's good electrochemical performance is due to the combination of mutual doping of Ni and Co with a mixed morphology. (c) 2021 Elsevier B.V. All rights reserved.
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