Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 900, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.163444
Keywords
Lithium-sulfur battery; Lithium anode; Lithium dendrite; Li-Nafion; Composite film; Uniform lithium deposition
Categories
Funding
- National Natural Science Foundation of China [52072099]
- Team Program of the Natural Science Foundation of Heilongjiang Province, China [TD2021E005]
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This study developed a composite protective film, Li-Nafion/Li2CO3 (LNL), to achieve a stable Li anode in Li-S batteries by redistributing Li+ flux, effectively inhibiting the formation of lithium dendrites. The Li-S batteries with LNL-5 film exhibited improved cycling performance and high rate capability.
The lithium-sulfur (Li-S) battery is considered as an appealing choice for the next-generation secondary battery due to its high theoretical energy density and low cost. However, the safety concerns and poor cycling performance caused by lithium dendrites seriously restrict its commercialization. A composite protective film with high lithium ionic conductivity has exhibited excellent inhibiting effect on the formation of lithium dendrites. Herein, Li-Nafion/Li2CO3 (LNL) composite film is developed to achieve a stable Li anode in Li-S batteries by redistributing Li+ flux. The Li-S batteries with LNL-5 film show an improved remaining discharge capacity of 730 mAh g(-1) at 0.1 C after 100 cycles and rate performance of 425.4 mAh g(-1) at 2 C. This work provides a rational design to suppress the formation of lithium dendrite for the stable Li anode in Li-S batteries. (C) 2021 Elsevier B.V. All rights reserved.
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