Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 901, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.163543
Keywords
Graphene coating; Birnessite; Oxygen vacancies; Cycling stability; Rate capability
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Funding
- National Natural Science Foundation of China [22075142]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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In this study, a novel nanoneedle-like rGO/V-NaxMnO2/CC cathode material with high capacitance and excellent rate performance was prepared by using a surface-protection strategy and introducing oxygen vacancies. It shows great potential as a new cathode material for aqueous supercapacitors.
Because carbon based supercapacitor electrode has low energy density, so birnessite electrode material has attracted more and more attention due to its low cost, environmental friendliness, high oxygen evolution potential and high theoretical specific capacitance. In this work, novel nanoneedle-like rGO/V-NaxMnO2/CC cathode material with oxygen vacancies has been prepared, where rGO and CC represent reduced graphene oxide and carbon cloth, respectively. By using surface-protection strategy and introduction of abundant oxygen vacancies, high capacitance of rGO/V-NaxMnO2/CC is obtained with 362.5 F g(-1) at 1 A g(-1). After the current density increases to 24 A g(-1), the capacitance retention is 56.56%, presenting excellent rate performance. In addition, after 10,000 charge discharge cycles at 5 A g(-1), the capacitance retention rate is 90.17%, showing excellent cycle stability. The aqueous asymmetric supercapacitor (ASC) of ACMK-3 // rGO/V-NaxMnO2/CC has a wide potential window of 0 similar to 2.5 V. And the energy density is as high as 72.2 Wh kg(-1) at 1254 W kg(-1). After 10,000 charge-discharge cycles at 4 A g(-1), the ASC still remains a capacitance retention rate of 88.5%. This work provides a facial method to improve electrochemical properties and shed a light on fabricating a novel cathode for aqueous supercapacitors. (C) 2021 Elsevier B.V. All rights reserved.
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