4.7 Article

NiS/activated carbon composite derived from sodium lignosulfonate for long cycle-life asymmetric supercapacitors

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 900, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.163546

Keywords

Sodium lignosulfonate; NiS; Activated carbon; Cycle life; Asymmetric supercapacitor

Funding

  1. Analysis and Testing Center, Shanghai University

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In this study, NiS nanoparticles were loaded on activated carbon derived from sodium lignosulfonate using a hexadecyl trimethyl ammonium bromide assisted hydrothermal method. The NiS/AC composite electrode exhibited improved conductivity, high specific capacity, and excellent rate performance. An asymmetric supercapacitor device assembled with NiS/AC composite as the positive electrode achieved high energy density and excellent cycling stability. These findings indicate the great potential of NiS/AC composites as electrode materials for supercapacitors.
In this paper, NiS nanoparticles had been successfully loaded on activated carbon (AC) derived from sodium lignosulfonate via hexadecyl trimethyl ammonium bromide assisted hydrothermal method. Due to synergistic effects of AC and NiS nanoparticles, the conductivity of the NiS/AC electrode is significantly improved, and the composite electrode exhibits a high specific capacity (677 C/g at 0.5 A g(-1)) and excellent rate performance. Moreover, an asymmetric supercapacitor (ASC) device was assembled with the NiS/AC composite as positive electrode and the AC as negative electrode to evaluate the electrochemical performance of NiS/AC composites in practical applications. The ASC device achieves a maximum energy density of 45.6 Wh/kg at a power density of 509.5 W/kg, and excellent cycling stability with 92.6% of capacitance retention after 20,000 cycles. The electrochemical performance suggests that NiS/AC composites have great application prospect as electrode materials for supercapacitors. (C) 2021 Elsevier B.V. All rights reserved.

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