Journal
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
Volume 37, Issue 7, Pages 1191-1214Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/01694243.2022.2062956
Keywords
Corrosion inhibitor; Calamintha oil; EIS measurements; AFM analysis; SEM micrographs
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In this study, essential oil of Calamintha (EOC) was extracted from Calamintha plant and its corrosion inhibiting effect on mild steel was evaluated using various electrochemical techniques. The results showed that EOC exhibited satisfactory efficiency in corrosion inhibition and the metal surface analysis indicated the formation of a protective barrier.
In the present work, essential oil of Calamintha (EOC) was extracted from Calamintha plant and characterized by gas chromatography-mass spectrometry (GC-MS) and FTIR technique. In addition, EOC was evaluated as an ecological corrosion inhibitor of mild steel in 1 M HCl medium by various electrochemical techniques. Satisfactory consistency was obtained between the gravimetric method, potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The maximum efficiency was recorded for the concentration of 1.5 g/L EOC which reached 87.57%. However, the morphology of the metal surface analyzed by Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) showed the appearance of a protective barrier on the steel surface. Finally, a theoretical study was carried out on the basis of the density functional theory (DFT) and molecular dynamics (MD) simulation technique.
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